ジムロート転位
1. Dimroth rearrangementThe Dimroth rearrangement is a rearrangement reaction taking place with certain 1,2,3-triazoles where endocyclic and exocyclic nitrogen atoms switch place . This organic reaction was discovered in 1909 by Otto Dimroth . With R a phenyl group the reaction takes place in boiling pyridine for 24 hours This type of triazole has a amino group in the 5 position. After ring-opening to a diazo intermediate, C-C bond rotation is possible with 1,3-migration of a proton.
Read “Dimroth rearrangement” on English Wikipedia
Read “ジムロート転位” on Japanese Wikipedia
Read “Dimroth rearrangement” on DBpedia
Read “Dimroth rearrangement” on English Wikipedia
Read “ジムロート転位” on Japanese Wikipedia
Read “Dimroth rearrangement” on DBpedia
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