Jisho

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転位
Wikipedia definition
1. Dimroth rearrangementThe Dimroth rearrangement is a rearrangement reaction taking place with certain 1,2,3-triazoles where endocyclic and exocyclic nitrogen atoms switch place . This organic reaction was discovered in 1909 by Otto Dimroth . With R a phenyl group the reaction takes place in boiling pyridine for 24 hours This type of triazole has a amino group in the 5 position. After ring-opening to a diazo intermediate, C-C bond rotation is possible with 1,3-migration of a proton.
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